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Metal-Free Catalyst TTT-DHTD Rivals Platinum in Zn-Air Cells

Indian scientists have built TTT-DHTD, a metal-free porous material that reaches about 96 per cent of platinum's performance in zinc-air battery electrodes.

By Published · 2 min read
Metal-Free Catalyst TTT-DHTD Rivals Platinum in Zn-Air Cells

Why in News

On 7 October 2026 the Ministry of Science and Technology announced that scientists at DST institutes and SRM University, Amaravati, had developed TTT-DHTD, a metal-free porous catalyst that performs nearly as well as platinum in zinc-air batteries.

A team of Indian researchers has made a porous organic material that does the work of platinum in a battery electrode without using any precious metal. The Ministry of Science and Technology announced the result on 7 October 2026, and the study has appeared in the journal Science Advances.

The problem it solves

In a zinc-air battery, oxygen drawn straight from the air reacts at the electrode in what chemists call the oxygen reduction reaction (ORR), and how well that reaction runs decides how well the cell runs. Such cells are attractive because zinc is cheap, plentiful and reasonably safe, and because the oxygen comes from the air, so no active cathode material has to be carried inside the battery. Against a lithium-ion cell they promise more energy for the same weight, lower material cost, better safety and less environmental strain, though rechargeability and cycle life are still being worked on. The catch has been the catalyst: most clean-energy devices, hydrogen fuel cells above all, lean on platinum, one of the rarest and dearest metals on earth, which keeps them expensive and hard to scale.

What was made

The new material, named TTT-DHTD, is built by joining two organic linkers known in short as TTT and DHTD. It uses only abundant elements — carbon, sulphur, nitrogen and hydrogen — and forms an extremely porous, honeycomb-like framework. Used as the air-electrode catalyst in a zinc-air cell, it reached roughly 96 per cent of the performance of commercial platinum catalysts. It also held steady through 120 hours of continuous running without the fouling or decay that often troubles metal-based catalysts. Computer simulations showed why: the molecular design creates sites where oxygen molecules settle and react easily.

Who did it

InstitutionsS. N. Bose National Centre for Basic Sciences, Kolkata; Institute of Nano Science and Technology, Mohali; SRM University, Amaravati
Lead researchersDr. Pradip Pachfule; Prof. Ramendra Sundar Dey; Prof. Ranjit Thapa
JournalScience Advances

The first two institutions work under the Department of Science and Technology. Replacing platinum with cheap organic matter could bring down the price of zinc-air cells sharply, making clean transport, portable power packs and storage for renewable electricity more affordable.

Important Facts

MaterialTTT-DHTD, a metal-free organic porous framework
ApplicationAir-electrode catalyst in zinc-air (Zn-air) batteries
ReactionOxygen reduction reaction (ORR)
Metal it replacesPlatinum
PerformanceAbout 96 per cent of commercial platinum catalysts
StabilityMaintained performance over 120 hours of continuous operation
Elements usedCarbon, sulphur, nitrogen and hydrogen
InstitutionsS. N. Bose National Centre for Basic Sciences, Kolkata; Institute of Nano Science and Technology, Mohali; SRM University, Amaravati
Lead researchersDr. Pradip Pachfule, Prof. Ramendra Sundar Dey, Prof. Ranjit Thapa
Published inScience Advances

Exam Point of View

Remember the catalyst's name TTT-DHTD, that it is metal-free and platinum-free, the figure of about 96 per cent of platinum performance, the 120 hours of stable operation, the reaction involved (oxygen reduction reaction), the three institutions and the journal Science Advances.

Practice Questions

Q1.Science & TechnologyEasy

The newly developed metal-free catalyst TTT-DHTD is designed to replace which costly metal used in clean-energy devices?

  1. A.Palladium
  2. B.Platinum
  3. C.Iridium
  4. D.Ruthenium
Show answer

Correct answer: B. Platinum

Explanation

The correct answer is platinum. Many clean-energy technologies, and hydrogen fuel cells in particular, depend on platinum to speed up the oxygen reduction reaction, and because it is one of the rarest and most expensive metals available, its cost and limited supply stand in the way of large-scale use. The newly reported organic framework matched about ninety-six per cent of the performance of commercial platinum catalysts while using no precious metal at all, which is why the work matters for the price of zinc-air cells. Options A, C and D name palladium, iridium and ruthenium, which are also costly metals used in various catalytic applications, but none of them is the metal identified as the benchmark and the bottleneck in this study. Candidates should link the material to platinum, to the oxygen reduction reaction and to zinc-air batteries together, since questions usually test one of these three links.

Q2.Science & TechnologyMedium

In laboratory tests, TTT-DHTD held its performance without decay for how long of continuous operation?

  1. A.48 hours
  2. B.72 hours
  3. C.120 hours
  4. D.240 hours
Show answer

Correct answer: C. 120 hours

Explanation

The correct answer is 120 hours. Tests showed that even after that long a spell of continuous running, the material kept its performance and did not suffer the degradation or contamination that commonly affects catalysts built around metals. This durability matters as much as the raw activity figure, because a catalyst that performs brilliantly for an hour and then decays is of little practical use in a battery meant for transport or for storing renewable power. Options A and B understate the tested period, while option D overstates it by a wide margin. Candidates should pair this number with the other headline figure from the same study, namely that the material reached roughly ninety-six per cent of the performance of commercial platinum catalysts, and should also remember that the simulations traced the result to sites in the molecular structure where oxygen attaches and reacts readily.

Q3.Science & TechnologyHard

TTT-DHTD was developed by researchers from which set of institutions?

  1. A.IIT Madras, IISc Bengaluru and CSIR-NCL Pune
  2. B.S. N. Bose National Centre for Basic Sciences, Institute of Nano Science and Technology and SRM University, Amaravati
  3. C.TIFR Mumbai, IISER Pune and BARC
  4. D.IIT Kanpur, JNCASR and ARCI Hyderabad
Show answer

Correct answer: B. S. N. Bose National Centre for Basic Sciences, Institute of Nano Science and Technology and SRM University, Amaravati

Explanation

The correct answer is S. N. Bose National Centre for Basic Sciences, Kolkata, the Institute of Nano Science and Technology, Mohali, and SRM University, Amaravati. The first two are institutions of the Department of Science and Technology, and the team was led by Dr. Pradip Pachfule, Prof. Ramendra Sundar Dey and Prof. Ranjit Thapa respectively, with the findings published in the journal Science Advances. Options A, C and D list well-known Indian research bodies, including engineering institutes, basic science institutes and national laboratories, but none of these combinations is the group credited with this particular material. Remember that questions on such announcements often ask either for the lead institution, for the parent department, or for the journal, so it is worth memorising all three: the Department of Science and Technology as parent, Kolkata and Mohali as the two institute locations, and Science Advances as the journal.

Frequently Asked Questions

What is TTT-DHTD?

A metal-free organic porous material made from two linkers called TTT and DHTD. Used as an air-electrode catalyst in zinc-air batteries, it reached about 96 per cent of the performance of commercial platinum catalysts.

Why is replacing platinum important?

Platinum is among the rarest and costliest metals and is the standard catalyst for the oxygen reduction reaction in fuel cells, so its price and scarcity hold back large-scale use of clean-energy devices.

Which institutions developed the material?

The S. N. Bose National Centre for Basic Sciences, Kolkata, and the Institute of Nano Science and Technology, Mohali, both under the Department of Science and Technology, together with SRM University, Amaravati.

Sources

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