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General ScienceMedium

Why does graphite conduct electricity while diamond does not?

  1. A.Graphite contains metal impurities
  2. B.Each carbon atom in graphite has one free electron
  3. C.Graphite is made of a different element
  4. D.Diamond has a lower melting point

Correct answer

B. Each carbon atom in graphite has one free electron

Explanation

The correct answer is B. In graphite every carbon atom is bonded to only three others within a layer, so the fourth valence electron of each atom is free to move along the layer, and moving electrons constitute an electric current. Option A is wrong because pure graphite conducts by itself; impurities are not the reason, and the same conduction is seen in synthetic graphite of high purity. Option C is wrong because diamond and graphite are both made of carbon alone, which is the whole point of calling them allotropes; only the arrangement of atoms differs. Option D is wrong because diamond actually has an extremely high melting point owing to its rigid three-dimensional network, and melting point in any case does not decide conduction. In diamond each atom is bonded to four others, so no electron is left free.

Read the full article: Carbon and Its Compounds: Bonding, Allotropes and PYQs

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