Which one of the following contains all Lewis acids?
- A.AlCl3, Co3+, BF3
- B.BCl3, NH3, OH-
- C.Mg2+, H2O, F-
- D.BF3, NH3, H2O
Correct answer
Explanation
The correct answer is A, AlCl3, Co3+, BF3. A Lewis acid is a species that accepts a pair of electrons, and all three of these can do so.
G.N. Lewis defined acids and bases in 1923 by electron pairs rather than by protons. Molecules with an incomplete octet are classic Lewis acids: in BF3 and AlCl3 the central boron or aluminium atom has only six electrons in its outer shell and readily accepts a pair, which is why anhydrous AlCl3 is used as a catalyst in Friedel-Crafts reactions. Metal cations such as Co3+, Fe3+ and Mg2+ also accept electron pairs from ligands to form complex ions. Lewis bases, in turn, are electron pair donors with lone pairs, such as NH3, H2O, OH- and F-.
B is wrong because NH3 and OH- are Lewis bases, although BCl3 is an acid. C is wrong because H2O and F- are Lewis bases, although Mg2+ is an acid. D is wrong because NH3 and H2O are Lewis bases.
Exam tip: Lewis acid = electron pair acceptor (BF3, AlCl3, metal ions); Lewis base = electron pair donor (NH3, H2O, OH-).
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