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General ScienceEasyAsked in: UPSC CAPF · CAPF 2017, Paper I

Liquid water is denser than ice due to

  1. A.higher surface tension
  2. B.hydrogen bonding
  3. C.van der Waals forces
  4. D.covalent bonding

Correct answer

B. hydrogen bonding

Explanation

The correct answer is B, hydrogen bonding. Hydrogen bonds lock the molecules of ice into an open cage, so ice takes up more space than the same mass of liquid water.

Each water molecule can form hydrogen bonds with four neighbours. When water freezes, these bonds hold the molecules in a fixed hexagonal lattice with a lot of empty space inside it. When ice melts, some of the bonds break, the lattice collapses and the molecules pack more closely, so the liquid is denser. Water is densest at about 4 degrees Celsius. This is why ice floats and why lakes freeze from the top down, leaving water below in which fish survive the winter.

A is wrong because surface tension acts at the surface and does not set the density of the bulk liquid. C is wrong because van der Waals forces are much weaker and do not build the open lattice of ice. D is wrong because the covalent O–H bonds inside each molecule are the same in ice and water.

Exam tip: ice floats because hydrogen bonds give it an open lattice; water is densest at 4 °C.

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