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General ScienceMediumAsked in: NDA · NDA-I 2025, GAT

Which one of the following statements is NOT correct?

  1. A.Half mole of nitrogen gas is measured 11.2 litre at STP
  2. B.17 gram of ammonia gas contains 6.022 × 10²³ molecules at STP
  3. C.22.4 litre of CO2 gas at STP contains 44 gram of molecules
  4. D.4 gram of hydrogen gas contains 6.022 × 10²³ molecules

Correct answer

D. 4 gram of hydrogen gas contains 6.022 × 10²³ molecules

Explanation

The correct answer is D. Four grams of hydrogen gas is two moles, so it contains 2 × 6.022 × 10²³, about 1.2 × 10²⁴ molecules, not 6.022 × 10²³.

One mole of any substance contains Avogadro's number of particles, 6.022 × 10²³. One mole of any gas occupies 22.4 litres at STP. The mass of one mole is the molar mass in grams: hydrogen gas (H2) is 2 g, ammonia (NH3) is 17 g, nitrogen gas (N2) is 28 g and carbon dioxide (CO2) is 44 g. So 4 g of H2 is 4 ÷ 2 = 2 moles, and the statement gives the number of molecules in only one mole.

A is correct because half a mole of any gas occupies half of 22.4 litres, that is 11.2 litres, at STP.

B is correct because 17 g of ammonia is exactly one mole and so holds 6.022 × 10²³ molecules.

C is correct because 22.4 litres of CO2 at STP is one mole, which weighs 44 g.

Exam tip: moles = given mass ÷ molar mass; one mole = 6.022 × 10²³ particles = 22.4 litres of gas at STP.

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Q1.General ScienceAsked in: UPSC CAPF · CAPF 2025, Paper IHard

Consider the following statements : 1. The circulation of nitrogen from the inorganic compounds in the soil to form protein in plants and animals and back again is known as the nitrogen cycle. 2. The preparation of ammonia by Haber process is an endothermic reaction. 3. Urea is synthetically made by the action of ammonia and carbon dioxide under high temperature and high pressure. Which of the statements given above is/are not correct?

  1. A.1 and 3
  2. B.2 and 3
  3. C.2 only
  4. D.1 only
Show answer
Correct answer: C. 2 only

The Haber process is exothermic, not endothermic: nitrogen and hydrogen combine to form ammonia and release heat. In the Haber process, N2 + 3H2 ⇌ 2NH3 gives out about 92 kJ for every two moles of ammonia formed.

Q2.General ScienceAsked in: UPSC CAPF · CAPF 2026, Paper IEasy

Which one of the following statements about xylem vessels in plants is not correct?

  1. A.Xylem vessels have lignified cell walls.
  2. B.Phloem sieve tubes are identical to xylem vessels in structure.
  3. C.Dead xylem vessels provide structural support to plants.
  4. D.Water is transported through xylem vessels.
Show answer
Correct answer: B. Phloem sieve tubes are identical to xylem vessels in structure.

Phloem sieve tubes are not like xylem vessels: sieve tubes are living cells with thin walls and sieve plates, while mature xylem vessels are dead, hollow tubes with thick lignified walls.

Q3.General ScienceAsked in: UPSC CAPF · CAPF 2026, Paper IMedium

Which one of the following effects best explains the high partial pressure of carbon dioxide causing haemoglobin to release oxygen in actively respiring tissues?

  1. A.Haldane effect
  2. B.Allee effect
  3. C.Bohr effect
  4. D.Eagle effect
Show answer
Correct answer: C. Bohr effect

The Bohr effect is the fall in haemoglobin's affinity for oxygen when carbon dioxide and acidity rise, so oxygen is unloaded where tissues need it most.

Q4.General ScienceAsked in: UPSC CAPF · CAPF 2026, Paper IEasy

Which one of the following statements about arteries is not correct?

  1. A.The inner lining is made of squamous endothelium.
  2. B.The middle layer is made of smooth muscle and elastic fibres.
  3. C.The outer layer is made of fibrous connective tissue with collagen fibres.
  4. D.Arteries have the thinnest walls amongst any other blood vessels.
Show answer
Correct answer: D. Arteries have the thinnest walls amongst any other blood vessels.

Arteries have the thickest walls of all blood vessels, not the thinnest, because they carry blood away from the heart under high pressure.

Q5.General ScienceAsked in: UPSC CAPF · CAPF 2025, Paper IMedium

Which one of the following is not an exothermic reaction?

  1. A.Dissolution of calcium oxide in water
  2. B.Decomposition of vegetable matter into compost
  3. C.Decomposition of lead nitrate
  4. D.Dilution of sodium hydroxide with water
Show answer
Correct answer: C. Decomposition of lead nitrate

Lead nitrate breaks down only when it is heated strongly, so the reaction absorbs heat and is endothermic. On heating, lead nitrate gives lead oxide, brown fumes of nitrogen dioxide and oxygen: 2Pb(NO3)2 → 2PbO + 4NO2 + O2.