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GK24
General ScienceMediumAsked in: NDA · NDA-II 2023, GAT

Which one of the following metals can be extracted using carbon as reducing agent?

  1. A.Zinc
  2. B.Silver
  3. C.Gold
  4. D.Aluminum

Correct answer

A. Zinc

Explanation

The correct answer is A, Zinc. Zinc lies in the middle of the reactivity series, so its oxide can be reduced to the metal by heating it with carbon (coke): ZnO + C → Zn + CO.

How a metal is extracted depends on its place in the reactivity series. Highly reactive metals such as sodium, magnesium and aluminium hold oxygen too strongly for carbon, so they are extracted by electrolysis. Metals of middle reactivity, such as zinc, iron and lead, are first converted to oxides by roasting or calcination and then reduced with carbon. Metals low in the series are found free or are obtained by simple heating.

B is wrong because silver is a low-reactivity metal found native or extracted from its ores by other methods, such as leaching with cyanide, without carbon reduction. C is wrong because gold is so unreactive that it occurs free in nature and is separated, not reduced. D is wrong because aluminium is more reactive than carbon and is extracted by electrolysis of alumina dissolved in molten cryolite.

Exam tip: top of the series by electrolysis, middle (Zn, Fe, Pb) by carbon reduction, bottom found free.

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