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General ScienceEasyAsked in: NDA · NDA-II 2017, GAT

Which compound, when dissolved in water, conducts electricity and forms a basic solution ?

  1. A.HCl
  2. B.CH3COOH
  3. C.CH3OH
  4. D.NaOH

Correct answer

D. NaOH

Explanation

The correct answer is D, NaOH. Sodium hydroxide dissolves in water and splits completely into Na+ and OH- ions; the ions carry current and the hydroxide ions make the solution strongly basic.

A solution conducts electricity only if it contains free ions. Strong electrolytes such as NaOH ionise fully, so their solutions conduct well. Whether the solution is acidic or basic depends on which ion it produces: H+ (more correctly H3O+) makes it acidic, OH- makes it basic. NaOH, also called caustic soda, turns red litmus blue and has a pH far above 7. It is used to make soap, paper and textiles.

A is wrong because hydrochloric acid conducts electricity but gives H+ ions, so its solution is acidic. B is wrong because acetic acid, the acid of vinegar, is a weak acid; it conducts weakly and its solution is acidic. C is wrong because methanol does not ionise in water, so its solution neither conducts electricity nor is basic.

Exam tip: free ions make a solution conduct; H+ makes it acidic, OH- makes it basic.

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