In which of the following pairs are the ions isoelectronic?
- A.Mg²⁺, Ar
- B.Na⁺, O²⁻
- C.Al³⁺, Cl⁻
- D.K⁺, Ne
Correct answer
Explanation
The correct answer is B, Na⁺ and O²⁻. Both have 10 electrons, the same number as a neon atom, so they are isoelectronic.
Isoelectronic species have the same number of electrons. Sodium has 11 electrons and loses one to form Na⁺, leaving 10. Oxygen has 8 electrons and gains two to form O²⁻, giving 10. Other members of this neon family are F⁻, Mg²⁺ and Al³⁺. Among isoelectronic ions, the one with more protons pulls the electrons in more tightly, so O²⁻ is larger than Na⁺.
A pairs Mg²⁺, with 12 − 2 = 10 electrons, with argon, which has 18.
C pairs Al³⁺, with 13 − 3 = 10 electrons, with Cl⁻, which has 17 + 1 = 18.
D pairs K⁺, with 19 − 1 = 18 electrons, with neon, which has 10.
Exam tip: count electrons as atomic number minus the positive charge, or plus the negative charge; 10-electron set N³⁻, O²⁻, F⁻, Ne, Na⁺, Mg²⁺, Al³⁺.
Practice Questions
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