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General ScienceMediumAsked in: UPSC CAPF · 7 Aug 2022

Hydrogenation of alkenes can be carried out in the presence of

  1. A.copper
  2. B.zinc
  3. C.aluminium
  4. D.nickel

Correct answer

D. nickel

Explanation

The correct answer is D, nickel. An alkene has a carbon-carbon double bond, and adding hydrogen across that bond turns it into the corresponding alkane. The reaction needs a finely divided metal catalyst, and nickel is the cheap industrial choice, usually at about 150 to 200 degrees Celsius; palladium and platinum do the same job at lower temperatures. The catalyst holds hydrogen molecules on its surface, splits them into atoms and lets them join the double bond, so it only speeds the reaction up and is not used up. The best known use is in food: unsaturated vegetable oils are hydrogenated over nickel to make solid vanaspati ghee. Option A is wrong because copper is used to dehydrogenate alcohols, which is the opposite kind of change. Option B is wrong because zinc dust is used for other reductions, not for adding hydrogen to a double bond. Option C is wrong because aluminium is not a hydrogenation catalyst at all. Exam tip: alkene plus hydrogen over nickel gives an alkane; oil plus hydrogen over nickel gives vanaspati.

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Q1.General ScienceAsked in: SSC CGL · 12 April 2022, Shift 1Easy

Which of the following is NOT a part of a flower?

  1. A.Petiole
  2. B.Pistil
  3. C.Stamen
  4. D.Sepal
Show answer

Correct answer: A. Petiole

Explanation

The correct answer is A, Petiole. The petiole is the stalk that joins a leaf blade to the stem; it belongs to the leaf, not to the flower, and a leaf without one is called sessile. A typical flower is built of four whorls borne on the thalamus. The calyx is the outermost ring of sepals, which protect the bud. Inside it the corolla of petals attracts pollinators. Then comes the androecium, the male whorl, whose units are the stamens, each with an anther on a filament. At the centre is the gynoecium, the female whorl, whose unit is the pistil or carpel, made of stigma, style and ovary. Option B is wrong because the pistil is the female part of the flower. Option C is wrong because the stamen is its male part. Option D is wrong because sepals form the calyx, the flower's outermost whorl. Exam tip: the four floral whorls are calyx, corolla, androecium and gynoecium; the petiole is a part of the leaf.

Q2.General ScienceAsked in: Bihar · BPSC Assistant 2014 Official PaperMedium

The oxidation number of Mn in KMnO4 is

  1. A.+2
  2. B.-2
  3. C.+7
  4. D.-7
Show answer

Correct answer: C. +7

Explanation

The correct answer is C, +7. Potassium permanganate is a neutral compound, so the oxidation numbers of all its atoms must add up to zero. Potassium, an alkali metal, is always +1, and each of the four oxygen atoms is -2, giving the oxygens a total of -8. Writing the balance as 1 plus x minus 8 equals 0 gives x as +7, so manganese is in the +7 state. This is the highest oxidation state manganese can reach, because it has seven electrons available in its 3d and 4s shells, and it is why KMnO4 is such a strong oxidising agent, used to disinfect water and to titrate in the laboratory. Option A is wrong because +2 is the state of manganese in MnCl2 or MnSO4. Option B is wrong because manganese is a metal and does not take a negative state in this salt. Option D is wrong because a -7 state is impossible for a transition metal here. Exam tip: in KMnO4 manganese is +7, and in K2Cr2O7 chromium is +6.

Q3.General ScienceAsked in: RRB JE · 29 Aug 2019 (ME, CBT 2 Paper 1)Medium

Coulomb friction is the friction between

  1. A.Two dry surfaces
  2. B.Two lubricated surfaces
  3. C.Bodies having relative motion
  4. D.Solids and liquids
Show answer

Correct answer: A. Two dry surfaces

Explanation

The correct answer is A, Two dry surfaces. Coulomb friction, also called dry friction, is the resistance that acts when two solid surfaces touch each other with no lubricant between them. Charles-Augustin de Coulomb set out its rules: the friction force is proportional to the normal reaction, it does not depend on the apparent area of contact, and it is very nearly independent of the sliding speed. Dry friction covers both the static friction that must be beaten before motion can start and the kinetic friction that acts once sliding has begun, and the limiting static value is the larger of the two. Option B is wrong because friction between lubricated surfaces is called fluid or film friction and obeys the laws of viscosity instead. Option C is wrong because relative motion describes kinetic friction, which is only one part of Coulomb friction. Option D is wrong because the resistance between a solid and a liquid is viscous drag. Exam tip: Coulomb friction means dry friction, proportional to the normal reaction and independent of the contact area.

Q4.General ScienceAsked in: RRB JE · 1 Sept 2019, Shift 1 (Electrical)Medium

Before starting electroplating, what action is to be necessarily taken?

  1. A.Buffing
  2. B.Soldering
  3. C.Cleaning
  4. D.Polishing
Show answer

Correct answer: C. Cleaning

Explanation

The correct answer is C, Cleaning. In electroplating the article to be coated is made the cathode, the plating metal serves as the anode, and both are dipped in an electrolyte containing a salt of that metal. When current flows, the metal ions travel to the cathode and settle on it. The coating can bond only if the surface is chemically clean, so grease, oil, rust and oxide are stripped off first by degreasing and by pickling in acid; any film left behind makes the plating peel, blister or come out patchy. Option A is wrong because buffing only brings up a shine on a surface that is already clean. Option B is wrong because soldering joins two metals with a filler alloy and has nothing to do with preparing a surface for plating. Option D is wrong because polishing smooths the surface mechanically but does not remove the oily and oxide films that spoil adhesion. Exam tip: the order is clean first, then plate, and the article is always the cathode.

Q5.General ScienceAsked in: RRB JE · 25 May 2019, Shift 3Easy

Which organ in the human body helps to maintain balance?

  1. A.Heart
  2. B.Liver
  3. C.Ear
  4. D.Tongue
Show answer

Correct answer: C. Ear

Explanation

The correct answer is C, Ear. Balance is controlled by the inner ear, which holds the vestibular apparatus alongside the organ of hearing. It is made of three semicircular canals set at right angles to one another and two small sacs, the utricle and the saccule. The canals are filled with fluid; when the head turns, the fluid lags behind and bends tiny hair cells, which send the brain a signal about the direction and the speed of the movement. The utricle and the saccule report the pull of gravity and straight-line motion. This is why an inner-ear infection, or spinning round quickly, leaves a person giddy. Option A is wrong because the heart only pumps blood through the body. Option B is wrong because the liver makes bile, breaks down toxins and stores glycogen. Option D is wrong because the tongue carries the taste buds and helps in speech and swallowing. Exam tip: the cochlea of the inner ear is for hearing, and the three semicircular canals are for balance.