Element X forms a chloride with the formula XCl 2 , which is a solid with high melting point. X would most likely be in the same group of periodic table as
- A.Na
- B.Al
- C.Mg
- D.K
Correct answer
Explanation
The correct answer is C, Mg. A chloride XCl2 means X has valency 2, and an ionic chloride with a high melting point points to a Group 2 metal such as magnesium.
Elements of Group 2, the alkaline earth metals (Be, Mg, Ca, Sr, Ba), have two electrons in the outermost shell. They lose both to form X2+ ions, which combine with two chloride ions to give MCl2, for example MgCl2 and CaCl2. These are ionic solids held by strong electrostatic forces, so they melt at high temperatures. The formula and the ionic nature together fix the group.
A is wrong because sodium, in Group 1, forms NaCl with valency 1.
B is wrong because aluminium, in Group 13, forms AlCl3, which is largely covalent and sublimes at a low temperature.
D is wrong because potassium is also in Group 1 and forms KCl.
Exam tip: Group 1 gives MCl, Group 2 gives MCl2, Group 13 gives MCl3.
Practice Questions
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