A vehicle fitted with a catalytic converter must use unleaded petrol because lead:
- A.Raises the temperature of the exhaust gases
- B.Inactivates the catalyst in the converter
- C.Reacts with carbon monoxide to form a solid
- D.Reduces the octane number of the fuel
Correct answer
Explanation
The correct answer is B, inactivates the catalyst in the converter. A catalytic converter holds platinum, palladium and rhodium on a honeycomb support, which oxidise carbon monoxide and unburnt hydrocarbons to carbon dioxide and water and reduce the oxides of nitrogen to nitrogen. Lead compounds from leaded petrol coat the surface of these metals and destroy their catalytic action, a process called catalyst poisoning, after which the converter no longer cleans the exhaust. Option A is wrong because the problem is chemical poisoning, not a rise in temperature. Option C is wrong because lead does not form a solid with carbon monoxide in the exhaust. Option D is wrong because tetraethyl lead was in fact added to petrol to raise its octane number, not to lower it. India therefore phased out leaded petrol before the tighter Bharat Stage norms, since the converter is the main device by which a modern engine meets them.
Read the full article: Air Pollution and Air Quality: Pollutants, AQI and Laws
Practice Questions
View allWhich of the following is a secondary air pollutant?
- A.Sulphur dioxide
- B.Carbon monoxide
- C.Peroxyacetyl nitrate
- D.Particulate matter
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A secondary pollutant is never emitted from a source; it is manufactured in the atmosphere itself when primary pollutants react with one another or with sunlight.
Read the full explanation →Which of the following is the chief component of photochemical smog?
- A.Sulphur dioxide
- B.Ozone
- C.Methane
- D.Carbon dioxide
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Photochemical smog, also called Los Angeles smog, forms in warm, dry, sunny weather when oxides of nitrogen from vehicle exhaust and unburnt hydrocarbons react under ultraviolet light.
Read the full explanation →Carbon monoxide is dangerous to human beings mainly because it:
- A.Combines with haemoglobin to form carboxyhaemoglobin
- B.Dissolves in water to form a strong acid
- C.Destroys the ozone layer of the stratosphere
- D.Settles in the alveoli as fine dust
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Carbon monoxide binds to the haemoglobin of the blood roughly two hundred times more readily than oxygen does, and the carboxyhaemoglobin so formed cannot carry oxygen.
Read the full explanation →Along with the oxides of nitrogen, which gas is chiefly responsible for acid rain?
- A.Carbon monoxide
- B.Methane
- C.Sulphur dioxide
- D.Argon
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Sulphur dioxide, released when coal and oil containing sulphur are burnt, is oxidised in the atmosphere to sulphur trioxide, which dissolves in water droplets to give sulphuric acid.
Read the full explanation →The damage to the marble of the Taj Mahal, popularly called 'marble cancer', is caused chiefly by:
- A.Carbon dioxide
- B.Sulphur dioxide
- C.Chlorofluorocarbons
- D.Ground-level ozone
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Sulphur dioxide from industry and traffic around Agra is oxidised in the air and comes down as sulphuric acid, which attacks the calcium carbonate of marble.
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