Which of the following elements has the largest-size atoms?
- A.P
- B.Cl
- C.Ar
- D.S
Show answer
Correct answer: A. P
Explanation
The correct answer is A, P. Phosphorus, sulphur, chlorine and argon all sit in the third period of the periodic table, so their electrons fill the same three shells. Moving left to right along a period, each element adds one more proton to the nucleus while the number of shells stays the same, so the nucleus pulls the outer electrons in more tightly and the atom gets smaller. Phosphorus stands furthest to the left of the four given elements, with the smallest nuclear charge, so it has the largest atomic radius. B is wrong because chlorine comes after both phosphorus and sulphur and is therefore smaller. D is wrong because sulphur lies between phosphorus and chlorine, so it is smaller than phosphorus. C is wrong because argon, a noble gas, is the last element of the period; its size is quoted as a van der Waals radius, which is measured differently and is not compared in this trend. Exam tip: size falls across a period, rises down a group.